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Electroanalytical Measurement Using Carbon Paste Electrode Modified TiO2/Ag-Li in Detection of Fipronil Compound

Muhammad Nurdin1,a), Thamrin Azis1, Sitti Hadijah1, La Ode Agus Salim2, Akrajas Ali Umar3 and Maulidiyah Maulidiyah1
The development of electrochemical sensors has become a topic that has been studied by many researchers, especially in improving the performance of carbon paste electrodes. This study aims to determine the performance of CPETiO2/Ag-Li in the determination of fipronil compounds by Cyclic Voltammetry (CV). The parameters electroanalytical are linearity, the limit of detection (LOD), lifetime, and real sample. The measurement of fipronil solution by CPE-TiO2/Ag-Li for LOD and repeatability with the Horwitz Ratio (HR) value were 0.01 ppm and 0.11%, respectively. The optimummeasurement stability of CPE-TiO2/Ag-Li in the detection of fipronil compound was 10 days. The interfering compound test using CuSO4 in analyte solution has a significant effect on fipronil analysis which was characterized by a decrease in peak oxidation current. The content of fipronil in the real sample obtained was 0.253 ppm. This research can potentially be used as an alternative pesticides control in agriculture in the future.

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Diterbitkan pada: The 3rd International Seminar on Science and Technology 2021 AIP Conf. Proc. 2719, 030012-1–030012-6; https://doi.org/10.1063/5.0133283 Published by AIP Publishing. 978-0-7354-4519-2/$30.00

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